I think many of us just haven't internalized the percentages of gasses, and probably, like myself, often have it all backwards. An alien doing a fly-through of our solar system would describe our planet as a nitrogen atmosphere.
In descending order:
Nitrogen: 78 percent
Oxygen: 21 percent
Argon: .9 percent
CO2: a measly 0.04 percent
Groking that last value really helps frame the challenges that CCS has to deal with (and also gives one an appreciation of just how powerful of a greenhouse gas CO2 is).