Of course. When I do my reps in the gym, I know I could do more if someone put a gun to my head. I stop because I don't want to hurt myself, not because I cannot do anymore. When I feel sleepy in the evening, I am fully aware that I could go 48 more hours without sleep if I really needed to. But would it be a good idea? No, it would not be.
And even if we ignore obvious health risk of pushing yourself to the limit, in general, I would rather be more comfortable than more productive. There are always things to be done, so why stress about doing a little bit more?