If there were only a finite number of such "True, but unprovable using your current proof rules" sentences, then you could simply add those sentences to your list of proof rules and there would be nothing "True, but unprovable" anymore. For Gödel's theorem to work, you need at least an infinite supply of those kinds of sentences.
Also here there's no need to actually write down all of them exhaustively. It's just important to be able to find "yet another one" whenever you would like to, which requires an inexhaustible supply.