There are definitely environments where "weird stuff" on the screen would get attention, but that will apply even if you're running Windows - it just has to look "hacker-like" enough. So I'm not sure disguising the desktop and the file manager will help if you still spend most of your time running shell commands.

If everyone in a workplace spends all their time on corp gmail (white background) and in terminal sessions to some mainframe somewhere (let's be generous and say teal text on black in like 20pt courier), anything that doesn't match either of those appearances will stand out pretty dramatically.