There are a lot of people (I'm looking at you, console home-brew community) who build all their little tools to go along with their projects as native GUIs, usually with C# + WinForms—not particularly because they have Windows-specific functionality, but more because they have at least some native functionality (so Electron is out) and C#+WinForms allows them to just make releases as a standalone .exe you can "just" download and run (at least on modern Windows), without needing to first install some external runtime.
This could be a good multiplatform alternative to the C#+WinForms stack, with all the same advantages. (The only con being that statically-linked Qt is pretty dang large.)