Lithium-Sulfur Battery Project Aims to Double the Range of Electric Airplanes
spectrum.ieee.org
spectrum.ieee.org
By contrast, biofuels are available today and can be made from agricultural waste products (2nd gen), in bioreactors using salt water algae (3rd gen) or electrochemically (4th gen).
They're potentially a drop in replacement for regular fuel - for planes, but also for cars.
Due to the lower energy requirements for building ICE cars versus batteries, a biofuel powered car will be much better for CO2 emissions than an electric one, which you need to drive for many years before it beats a similar sized gasoline fueled car on sum CO2 emissions.
So why are we not heavily investing in biofuel infrastructure? Why are electric motors and batteries hyped up as being the tech of the future? That's an honest question, since I've yet to hear a well-founded physical or engineering argument against it.
Can we turn solar energy into hydrocarbons? (Water and CO2 are total feedstocks.)
Hydrogenate CO2 to methanol with electrolytic hydrogen produced from clean electricity [1]. Reform methanol to hydrocarbons [2] that can burn in existing engines. (Or burn methanol itself in slightly modified engines. This offers somewhat lower energy density per tankful of fuel, higher total efficiency from electricity-to-motion.)
Synthetic fuel makes sense for fueling aircraft, rockets, long distance shipping, collectible historic cars, and other niches. It doesn't make sense for fueling everyday ground transportation. Too much of the original energy is lost in the chain of chemical transformations and the chemical processing requires facilities on the scale of conventional oil refineries. The total cost is lower to electrify ground transportation and supply it with clean electricity than to transform clean electricity into liquid fuels for equivalent legacy vehicles.
[1] https://www.frontiersin.org/articles/10.3389/fchem.2018.0044...
What's driving the emphasis on lightweight batteries for aviation over better synthesisation?
- Extremely long flight endurance without refueling (in large solar/battery UAVs)
- Low noise
- Odorless
- Simpler and cheaper manufacturing
The advantages are much less obvious to me for aircraft that transport passengers or significant cargo loads. I suppose that the companies developing them are hoping to make the lifetime total cost of operation cheaper than existing aircraft serving the same niche. That seems much tougher to achieve.
EDIT: Bye Aerospace, the company described in the IEEE article, says they are targeting a particular niche:
https://byeaerospace.com/eflyer/
They intend to replace trainer aircraft that burn leaded aviation gasoline. This polluting niche fuel costs significantly more than kerosene. Maybe the economics can work out for this case.
How efficient is producing biofuels using renewable energy as a way of storing power long term?
For your comparison between ICE and electric vehicles, are you counting the fuel processing and delivery infrastructure? Electric delivery infrastructure has very low emissions once it's in place, and production continues to get better (especially with distributed models like rooftop solar). Also, do you have a citation for "...lower energy requirements for building ICE cars versus batteries"? Yes, battery production is fairly intensive (economically and resource use), but (like I said above) the drivetrain is vastly simpler.
I can't see how electric general aviation will become widespread without a monumental breakthrough. But it's hard to beat electric for ground-based transportation, IMHO.
https://www.carbonbrief.org/factcheck-how-electric-vehicles-...
Check out the "lifecycle greenhouse gas emissions" figures. It's really interesting in how it shows how different the total emissions are depending on which country you charge your electric car in. Also, depending on which electric car model you have, the lifecycle emission improvement over a conventional one might be relatively slim, depending on where and how much you drive it.
By and large, electrics are at a substantial disadvantage due to both battery production and fuel cycle emissions, which then gets compensated over time as you drive the car.
Edit: There's also this super interesting article on Wikipedia: https://en.wikipedia.org/wiki/Environmental_aspects_of_the_e... which is largely consistent with the Carbonbrief article.
Lifecycle greenhouse gas emissions for conventional and electric vehicles (by country) in grammes CO2-equivalent per kilometre, assuming 150,000 kilometres driven over the vehicle lifetime.
That's less than 100,000 miles - rarely do cars travel less than that during their lifetime.
Specifically in my country that would mean using the car for ~10 years, meanwhile the average passenger vehicle age is 14 years!
As for biofuels: land and water usage are major hindrances. For example you need ~1800 liters of water to grow 1kg of soybean. Sure, you can use waste products for fuels, but they need to be waste from something.
What's the GHG emissions for the different types of biofuels ? What's the land use needed ? How abundant ? Etc.
This is still less of an issue as the electric motor can spin faster due to the reduced resistance. Higher speeds will create higher resistances from within the motor itself (which will in turn be increase the heat generated in the motor).
That heat will also be harder to dissipate in lower pressures, but I suppose alternative cooling could be added as well.
Using large radiators on an electric engine kinda defeats the purpose especially when they can’t be effectively be built into the body of the engine.
Plus you'll probably want to recover some of that waste heat to heat the cabin.
source: https://www.aopa.org/news-and-media/all-news/2019/may/flight...
Does the RPM of the electric engine matter if the RPM of the propeller can't exceed a certain rate (because the tips of the prop will break the speed of sound, which you generally don't want for comfort reasons)? I mean this in terms of power generation and pushing air.
Beyond a certain RPM range electric motors lose torque. Eventually you'd reach the limits of the bearings or the maximum centrifugal force that the rotor can withstand, but that's usually at a higher RPM than gas engines are made to survive. I would expect an electric motor designed for an aircraft would be optimized for maximum power/efficiency at whatever RPM band is optimal for the propeller, and the battery would be optimized for whatever voltage is optimal for the motor at that RPM range.
Yes, but air-density-altitute problems are identical no matter what is spinning the prop, righ?
> This is still less of an issue as the electric motor can spin faster due to the reduced resistance. Higher speeds will create higher resistances from within the motor itself (which will in turn be increase the heat generated in the motor).
OK, so do the math for me here, I am a bit confused. I am not a motor whiz, but torque at the output converted to watts is going to be power at the input less i^2*r losses. The back-EMF will go up as the motor speeds up, so it may be at a somewhat less efficient point on the RPM-versus-torque curve, but the resistance of the actual wires doesn't change.
> That heat will also be harder to dissipate in lower pressures, but I suppose alternative cooling could be added as well.
I think that is all true. Seems to me you design cooling around the cooling capacity of the air flow at max operating altitude. Is that really a huge design constraint?
The batteries may produce as much heat as the motor, and they have a more limited temperature range. Their service life decreases when run above 40 C. Tesla batteries are liquid-cooled.
But discouragingly, just last August, in Norway, a Pipistrel Alpha Electro lost power shortly after takeoff and crashed. https://aviation-safety.net/wikibase/228207
Hopefully, these folks in Fresno, CA will get their electric aircraft flight school up and running sometime soon. But summertime in California's central valley is challenging: https://sustainableaviationproject.com/2018/10/28/we-hit-the...
Not to mention it makes a lot less weight to lift; the difference is huge.
Additionally 1st gen biofuels have poisoned the well to some extent due to competing with food crops.
Short answer: Monied interests don't really care, or don't think it is possible or feasible.
Biofuels make sense I think for aviation because you need that energy density to get a usable range, but the fuel is likely to be expensive for a long time. If you can figure out how to make liquid fuel for about fifty cents a gallon or so, it might be competitive with electricity for car use.
I don't know what the energy requirements are for modern batteries, but I expect it varies a lot depending on battery chemistry. Battery sizes vary a lot, too.
One nice thing about electricity is that it's much cheaper than biofuels. This is because motors are much more efficient than engines, and because large generating stations are more efficient than small aircraft engines. BC is 95% hydroelectric which makes electricity even cheaper.
I think the problems are more economics than physics. There was a huge investment in algal biofuels but it never proved economic. (eg https://www.greentechmedia.com/articles/read/lessons-from-th...)
I was a fan of Algenol for a while who were supposed to have algae that gave off ethanol cheaper than normal fossil fuel but it never worked out. Maybe something like that in the future will work.
https://i.imgur.com/nZSWpW1.png
Should be very interesting if they can deliver that level of performance.
The source document for that graph is here: https://ethz.ch/content/dam/ethz/special-interest/mavt/robot...
And described here: https://spie.org/news/1649-designing-solar-airplanes-for-con...
23,222,915,000 wh/kg (plutonium 239)
https://en.wikipedia.org/wiki/Energy_density#Table_of_energy...
Instead of the pyramid of fuel mass needed to escape a gravity well, the capsule would basically be constant mass.
An antimatter-powered spaceship could conquer the solar system or even the universe.
The Airbus Zephyr was using lithium-sulfur batteries back in 2015:
https://cosmosmagazine.com/technology/lighter-cheaper-satell...
Also, depressurization happens, and the risks and complexity of workarounds increase with altitude.
Actually none those two planes had fully pressurized cockpits. I guess they were pressurized at 26k feet altitude pressure. That's why the pilots were literally wearing spacesuits.
The space suits weren't because of the cockpit altitude (when the cockpit was pressurized), they were because the crew were operating well above the Armstrong Limit and no amount of oxygen could keep them awake in the event of depressurization without the suit.
I flew a Cessna 206U for a few years and it was fine up to 15k feet or more, but I'd almost always skim just below 10,500 so I didn't have to bring along supplemental oxygen. I suspect that's where most of these guys will live, in the 7,000-10,000 foot range. It's much faster then flying near sea level but without the problems with O2.
Every airliner notices this when climbing, you get closer to the Mmo speed (maximum Mach number for operating) while at the same time the IAS decreases and you get closer to a stall due to decreasing airdensity. At some point you cannot go faster due to maximum Mach while you also cannot go slower due to minimum IAS to avoid a stall. At that point you cannot climb higher even if your engines have the power.
https://www.ncbi.nlm.nih.gov/pubmed/12862322 https://www.cdc.gov/niosh/topics/aircrew/cosmicionizingradia... https://www.cdc.gov/nceh/radiation/air_travel.html
> METHODS: A cohort of 10,051 male and 160 female airline pilots [...] was followed for cancer incidence [...].
> RESULTS: Among male pilots, there were 466 cases of cancer diagnosed vs. 456 expected.
So, a heightened risk of (466-456)/10051 = 0,001% if I read this correctly.
Or am I misunderstanding something here? I guess so, because this seems close to negligible.
However, to make it feasible for commercial air travel, you need much faster charging times, because airlines want to have as short of a turnaround as possible for their planes.
But I can totally see how electric planes would work for hobby piloting in the first place.
It's a ferry replacement.
Things like refueling speed, the weight of the batteries themselves (which don't burn up as you consume them like combustibles, and the overall better energy density of combustibles probably make the whole thing more attractive at today's tech.
https://github.com/gusgordon/atmosat/blob/master/atmosat.ipy...
https://github.com/gusgordon/electric_jet/blob/master/plane....
[1]: https://en.wikipedia.org/wiki/Lift_(force)#Lift_coefficient
Lift = weight = 0.5 * \rho * v^2 * S * C_L
Power = drag * speed = 0.5 * \rho * v^3 * S * C_D
where \rho is the air density. A good assumption for cruise is (C_L/C_D)_max. If you do the math, you realize that for a constant weight, the power output must be proportional to:
Power \propto \rho^{-0.5}
For example, to fly a plane at 10km above sea level you need twice as much power than sea level. This is totally independent of your propulsion system.
There is an upside though. Subsonic aircraft can go faster as the temperature rises because the speed of sound increases. It goes from about 295 m/s to 329 m/s. The extra 11% is nice.
Graph of the air by altitude: https://upload.wikimedia.org/wikipedia/commons/9/9d/Comparis...
For comparison the energy density of gasoline is 12,200 Wh/kg
But surely that is largely due to the electric element of the combined powertrain? The ICE part hasn't magically become more efficent?
So yes, the ICE part is more efficient in a hybrid, though it isn't magic.
Here's a single example with the Prius:
1. The intake valve stays open for part of the compression stroke.
2. (1) means that the compression ratio for the compression stroke is lower than the compression ratio for the power stroke.
3. The efficiency of the engine is limited by the compression ratio of the power stroke
4. The compression ratio of the compression stroke is limited by engine knocking (if you compress a mixture of fuel and air too much, it will spontaneously combust)
5. So this engine can be made more efficient than an engine that closes the valve for the entire compression stroke
6. Some (non-hybrid) engines have variable valve timing and can do (1) some of the time, to a small extent.
7. Doing (1) to a larger extent makes the low-RPM torque very poor.
8. Electric motors have excellent low-RPM torque, so (7) is compensated for by having an electric motor run at low speeds.
Over 30% efficiency for gasoline, and over 50% for diesels.
Electric motors are lighter than ICE engines per HP and torque unit.
Emrax 268 (electric engine designed for aircraft) - 6.12 HP/lb
GE 90-115B (jet engine used in 777) - 6.10 HP/lb
Junkers Jumo 205A (diesel engine used in Ju 86C-1) - 0.66 HP/lb
Electric also scale down better so for light weight UAV a higher energy density battery will open up a bunch of use cases.
Looking things up, I see different numbers for electric motor efficiency, ranging from the low 70s to the low 90s percent. As an overly simplified example, let's assume an electric motor in a car has an efficiency of 80% (in reality, they may be better). At that efficiency, a battery pack only has to get to 5032.5 Wh/kg to achieve the same practical energy density as gasoline, less than half the actual raw energy density. That is probably an easier number to reach than trying to achieve the same raw energy density of gasoline.
Nobody has made this argument in this thread (yet, as I type this), but I've seen it made before and made it myself. Yes, at those energy densities, batteries are highly dangerous if something goes wrong (like a crash) and they release all their energy at once, but so is gasoline. At practical ranges, you're potentially sitting on a pile of high-explosives either way. But, I'd hope a 5032.5 Wh/kg battery is easier to make safer in a crash than 12,200 Wh/kg gasoline is.
[1] https://newsroom.toyota.eu/new-2019-toyota-prius-with-intell...
the other benefit is the weight of gas goes down as the flight progresses which is about 1/3 of the total weight so make the design a bit worse but I believe it would still be compensated by cheapness of solar electricity based charging.
on a related note, IMO this is the reason the whole fuel cell shtick from toyota is BS. Because if it were anywhere near economical & scalable then we would be seeing fuel cell powered drones all over.
I was thinking in terms of passenger cars for some reason (despite the word "airplane" being in the title), where piston engines are far more common than turbine engines. That said, I stand by the main point of my post, which is that you can't just consider the energy density of your energy source in isolation, you have to also account for the efficiency by which you convert that energy source to useful work.
A thing I find myself wondering about now is the viability of an arrangement similar to that of cargo trains. IIRC, the locomotive of cargo trains is a hybrid of sorts. An internal combustion engine running at relatively high efficiency drives a generator, which in turn powers electric motors which drive the wheels. This sound similar to your hybrid idea, perhaps with the addition of batteries.
I think one of the biggest challenges to hybrid systems is to make sure the overall system efficiency doesn't drop below that of the current typical systems which it is intended to replace. Say you have a plane with turbojet engines running at 60% efficiency. And we replace it with a charging turbine-engine at 70% efficiency, coupled to an 80%-efficient charging system, coupled to a 90%-efficient electrical engine. In isolation, each of those numbers sound better than the 60% efficiency of the turbojet engine. However, efficiencies combine multiplicatively, and so 70% * 80% * 90% = 50.4%. That's overall worse than the turbojet we started with. This new system better be much lighter than a turbojet to be worth it.
Turbines are not used in cars because they have high rpm and low torque requiring large transmissions to gear them down properly. They also are not very responsive to throttle requiring spin up, very noisy and have have an abundance of hot exhaust to deal with. You can't muffle them as easily.
Series hybrid diesel electric trains are actually less efficient than diesel mechanical drive trains. They are used because of the need for precise traction control to prevent wheel slip, they sacrifice efficiency at speed though to attain it.
Double conversion from mechanical to electrical back to mechanical will always be less efficient than a straight through mechanical drive once up to speed, this is why nearly all hybrid cars are parallel and go full mechanically coupled at highway speed.
As far as I know, there are simply no rechargeable battery chemistries that have any (even theoretical) hope of achieving this level of specific energy.
If you can make up in other areas like drag in the design because of the different power plant it's not such a mental gap to close.
1. sulfur plating the anode? 2. The cathode swelling during charge and mechanically damaging the cell?
If so, I'm excited! But last I checked thier solution to #2 was to clamp the cell between metal plates, which nullified the gains in energy density when considering the mass of the clamps.
Curious, have you ever heard of Boron-Nitride Nanotubes (BNNT)? Basically a new nanomaterial that is similar to carbon nanotubes except it has the rare property of being a high energy band-width semiconductor whilst having excellent thermal conductivity (basically solves problems 1. and 2.). Only problem is that its really hard to produce in mass quantity... well maybe... have a look at the company PPK
I do not think lithium or a chemical battery is the right solution. Too expensive and polluting. I am hoping for a silicon battery that will take over the world.
So now it should be a golden age to be a chemical engineer or a physicist specialising in battery technology research I suppose.
> I am hoping for a silicon battery that will take over the world.
Chemical Engineers and Battery Technologists will be the new 'Software Engineers'.
1. Noise pollution could be significantly reduced . So many flight paths over homes.
2. Cost efficiencies could be amazing with fuel anywhere from 25% - 35% fluctuations, https://www.statista.com/statistics/591285/aviation-industry...
I imagine the operating cost of electric would be even less due to the simpler design of engines for electric vs gas
In my dreams airplanes could be designed to be more comfortable due to fixed operating costs... that would be nice
The pace of their progress is not jaw-dropping, but if anyone has a shot at bringing this chemistry to the market, it's them.