The consensus model of blockchain would at least require Mastercard, Andreessen Horowitz and other validator nodes to be in agreement about stealing / being entitled to the money, which seems less likely. That said, this is one of the flaws of having only a few nodes validating transactions. Libra went this route instead of Bitcoin's proof of work consensus model. With Bitcoin's proof of work consensus, 51% of the miners in the world would have to collude in order to steal funds.
All of the comments I see that say blockchain has no use case, seem to miss another point you raise, in that Bitcoin can not be seized, even by government (like the US government did with Gold), unless they had miner control and the public didn't continue to operate and spin up new miner nodes. This seems unlikely considering that the miners could lose their funds, if they did not prevent a counterparty having 51% control of the network. This is a protection that Bitcoin has, that Libra does not. The government could go to corporations in the Libra association and tell them to do what they want.
In terms of other use cases, I think having an immutable ledger, that can't be changed by one party, or even a few parties with DB access, also seems like a compelling use case for blockchain / cryptocurrency. Libra isn't really a cryptocurrency by this standard though, although Bitcoin is.
Also, just to put it out there, Mastercard, PayPal, Stripe, Visa and a few others already have left the Libra association.