Reflective roofs/walls of buildings, basically make more IR and heat energy get reflected away from the surface.
You don't really make the atmosphere thinner by removing CO2 or methane...they are trace gasses relative to N2 and O2, CO2 is less than a .05% of the atmosphere, IIRC. So, you mostly want to prevent heat from hitting the Earth, or decrease the absorption (increase albedo), or you want to remove the heat-trapping gasses that will continue a warming cycle by trapping the heat we do get.
I think space sunshade's a decent idea, but we still need very aggressive decarbonization, as CO2 is very bad for the ocean, nevermind the heat trapping.