The most obvious, and applicable in any climate and weather, is domestic hot water heating. Temporarily suspending power to electric hot water heaters at times of high demand can save tons of short-term load. And, it's potentially responsive enough to support frequency control ancillary services (the very expensive task of keeping the power grid running at exactly 60Hz or 50Hz when power demand is changing fast).
Another is electric vehicle charging time-shifting, either mandatory or voluntary.
A third, more complex, opportunity is HVAC. If heating / airconditioning systems can get ahead of their needs during late afternoons, then temporary power suspension in early evenings is feasible. This kind of application may be easiest to deploy in commercial locations like big-box stores, office buildings, and data centers.
A mindset change required is this: demand time-shifting IS energy storage.
A bigger mindset change: grid operators are in the information business, whether they know it or not. All this proposed timeshifting is based on information.