TL/DR: Book appointments on your calendar to get work done and stick to them. Shut off notifications while you're in there.
I've been working from home for a decade now, and basically I think this is bonkers (no offense, I see the founder is here posting). With all the tools out there if you really want to do that pair up with a coworker and do it with an existing tool. I don't work in pajamas or do anything dumb but I have zero (0) interest in having someone I don't even work with having a video feed into my house. That's as a man, don't even get me started on how uncomfortable I'd be if I wasn't a cis / straight guy.