Almost all of these concepts could easily be learned in a few weeks by a talented engineer with strong fundamentals in software design and computer science.
Polyfills aren't exactly quantum mechanics. They're not some radically different mental paradigm that takes years to develop fluidity. If you already have a sound basis in the major software engineering concepts, learning polyfills is just a matter of reading the docs to learn the details.
Let's not forget that Jordan Walke was working on back-end infrastructure code just prior to inventing ReactJS. Miso Hevery was working on Java testing frameworks just before inventing AngularJS. So it's not like there's a history of front-end being such a unique problem domain, that it's impossible for outsiders to pick up.
The only major sub-domain of software that I think this may potentially be true of is embedded systems. And even then, that's a big maybe.