The radio technology involved should have almost nothing to do with the ability to perform a relay attack. There are two straightforward mitigations:
1. Timing. The two parties confirm that a message can round trip in a specified, very short time T. This proves that the distance between the parties is T/2c or less.
To be useful, T should be, say, 20ns or less, which requires a bit of clever crypto to make the actual exchange fast enough.
2. The transmitter attempts to localize itself, using GPS or other technologies, and refuses to authenticate unless it’s near the receiver.
There is reason to believe that UWB will help with localization. I see no reason it would be any better than any other technology for time-of-flight measurements unless sub-nanosecond resolution is needed.