I take it you mean Uber? I find it hard to believe Slack has 27000 employees.
Anyway, as another commenter pointed out, on an enterprise scale I'm sure you can get a good deal. I can also imagine however that at that scale you'll want multiple Slack servers / instances - which would add cost given how slack charges per person, per server.
So there's a few alternatives then; self-hosted (some parties will offer enterprise customers the option to host an instance of their application on the customers' internal hardware), or rebuild it yourself. The latter one however takes a bit of math - how much is it going to cost to build, maintain and run it? It's easily underestimated.
And yet, it's also easy for people working in an engineering culture with nearly limitless engineering capacity to just build it themselves - motivations being "how hard can it be", and "I need something more challenging than tweaking this button for my employer to earn 0.1% more money on this particular feature". I've seen it happen far too often.