To me, solar is first-order. Solar leads to wind, so it's second-order. (Though really, solar heats water and air, producing wind, so it's kinda third-order.) Oil is... uh... the sun grows the plants which die and get compacted, then we pump up the remnants. I'm not sure what you'd call that.
Uranium is, like, zeroth order then. Fusion in the Sun produces solar.
And yet, none of this really means much. Unless you're constructing Dyson spheres, it really doesn't matter how efficiently you're capturing the max theoretical energies. If you don't believe me, stop eating. Try replacing food with sucking on a power cord.