The same thing with MPG: 5L/100km is about 56mpg, so for the same trip to London we'll need about 5.5 gallons. Which is great to know except that I have no idea how much is a gallon from the top of my head. I have to Google it, apparently it's about 3.7 litres? But....that's not right, the figure is now different. Ah. US vs UK Gallon, and of course Google shows me US Gallon as a result for gallon, despite knowing I'm in UK. Imperial gallon is 4.5L and now we arrive at the same number of 25L for the trip.
It's not impossible, I just find the first way much easier to work with.