I've got a similar thing with my postfix setup though. My users can go to their account portal and apply for an alias, which when approved (to avoid taking of important names like postmaster etc.) is added to their otherMailboxes LDAP attribute. They can delete the alias themselves when they're done with it.
I'm tempted to start auto-allowing new aliases and just having a list of names that can't be used (postmaster, webmaster) etc, that some services use for domain ownership verification.
As an aside I do hope qmail offers similar limiting abilities. It wouldn't be great if a user could make themselves receive webmaster@domain.tld emails!