Spreadsheets, common. "maintained really well", not so common, so that's great!
Congratulations, you joined a very resourceful company that was able to concentrate ruthlessly on their product-market fit by leveraging the tech that they knew.
Now you can take all the spreadsheets and the glue code, and then cover the entire system with behavioural end-to-end tests.
Then you get to pick one part at a time and develop a replacement with a more standard stack, keeping the old and new part running in parallel, looking for differences in behaviour in order to discover functionality hidden in the spreadsheets and add to your test suite.
Then when it's all done you have a great story to tell about how you took a startup that had a great product-market fit but an unorthodox stack and migrate it to something that let the company hire from a more accessible pool of devs.