In case someone reads this and gets the impression that running PG over NFS is in general safe or a good idea, I'm pretty sure it still isn't, unless like the OP you have a complete understanding of what you're doing.
You're right though: you really do want to have some idea what you're doing, if you're going to go there.
Source: my day job is PostgreSQL DBA, and has been for ~15 years now.
EDIT: Phrasing.
As an FYI - we no longer use Postgres on NFS as we have migrated the entire architecture underlying the systems in question.