People and animals have been asphyxiated by massive CO2 releases because they can happen very quickly, and CO2 has a molecular mass of 44, making it stay near the ground for longer, displacing lighter oxygen and nitrogen gases.
0.656 kg/m³ methane
1.98 kg/m3 carbon dioxide
1.225 kg/m3 air.
Quick look indicates asphyxiation at 16-21%. At 5-15% concentration it is explosive. Current levels are about 2000 parts per billion.
It will not release that quickly on anything more than a localized level, and it would probably kill you via explosion, first. Since it would be gradually released we would all be long dead from the greenhouse effect.
[1] https://news.nationalgeographic.com/2018/01/climate-change-s...
Maybe not gas clouds of rolling death, but some think it would be pretty catastrophic.