I know -- that's what I was trying to convey when I said "pay your taxes or other bills", because those are (pretty much) the only times when you can require someone to accept money from you, and consequently the only times the concept of "legal tender" could even possibly come into play. Even then, most creditors are happy to take payment in any convenient form :).
Most of the time most of the people are happy to accept anything that's a properly denominated bank note. But while I'll happily try to spend Scottish notes down South, there's no requirement on any shops to accept them.
Edinburgh Council have recently done something interesting though: they've stopped (in most locations) accepting cash for payment of bills. Now I'm wondering if I should cancel my direct debit and take them a stack of pound coins :).