Only if that minute of arc lies on a great circle route.
As an interesting addendum, when measuring distance made good on a nautical chart, you will use a divider to measure the straight line distance, then lay this onto the latitude scale to convert it to nautical miles.
If you were to use the longitude scale, you would be off by approximately the cosine of your latitude, because the lines of latitude() (apart from the equator) are not great circles.
() corrected longitude to latitude here - longitude is obviously great circles, latitude apart from the equator are not.