Proposed solution - `a[0] if a else None`
Your reaction - Python doesn't offer a rich standard library.
I disagree, and I suspect most programmers would too. We'd much rather have ergonomic libraries to make http requests, parse command line arguments, datetime, itertools, data structures like heaps, filesystem access, data archiving, data serialization and deserialization and a million other nice-to-haves. It's actually at the point where I've heard criticism of Python's stdlib doing too many things, rather than too few.
If you don't want to write 19 characters to find the first item in a list, pick another language. But don't mischaracterise python's standard library.