I'm quite skeptical on supplements, but I have to say that Magnesium helps me sleep like a baby and feel much more relaxed generally.
Do you know why Mg helps you so much?
But yes, glycine also has many of its own benefits. Including a very interesting theory regarding life extension due to its interaction with methionine. [2]
[1] https://examine.com/supplements/glycine/#nutrient-nutrient-i...
[2] https://www.fasebj.org/doi/abs/10.1096/fasebj.25.1_supplemen...