Interesting stuff!
I recommend starting the batteries out at full. Otherwise it seems you always have curtailment early on... Seems more realistic (charged batteries don't weigh any more than empty ones).
Also, what about fuel cells that run on CH4? It would be interesting to model that. How much CH4 / batteries / solar do you need to kick-start a self-sustaining Sabatier-based colony? Could CH4 storage replace battery storage?