Because they perform well up until the point that they don't. By working at $Company, you're already invested heavily in their success. If a substantial portion of your net worth is also tied up in their stock, the company having problems may ruin you. Imagine: the stock price tanks due to some real issues, and then you get laid off. In one swoop you've lost both your salary and your savings.
If you'd instead sold some or all of your stock, you'd have a solid nest egg to fall back on. And companies doing very well up until the point that they suddenly explode is not exactly unheard of: consider Enron, or even Groupon or Zynga.
It's true that it's unlikely for FB to implode over the next year, but last year was real rough for the company: the July earnings went from 220 to ~160. If your whole savings is wrapped up in that, that's a scary drop. (You can say that it's recovered, but only partially and slowly).
Long story short: it's easy to pick the winners if you're looking backwards.