Current economics are based on the notion that fuel is expensive and therefore you try to fly huge planes with lots of people because it delivers better fuel economy. This completely dominates everything in the aviation industry currently from design, logistics, to operations. The economies are such that you only fly routes where you can fill all the seats and still pay for the fuel. With electric your energy cost is a much less significant. Your main cost shift to infrastructure, cost, maintenance, etc. of the plane. If electric cars are an indication, you can expect some reduced cost there as well.
So, suddenly, flying short hops with small air planes becomes cheap and feasible. So, why fly short hops with a few huge planes that cost tens of millions and burn tons of fuel when you can fly the same route with many smaller planes that you charge using solar/wind/etc. for a fraction of the cost? Changes the game completely. E.g. London-Amsterdam could be dozens/hundreds of 6-12 seater electrical planes instead of a handful of airbuses flying back and forth. Also, London City suddenly becomes more attractive because small electric planes are not so noisy.
Basically on board staff becomes the limiting factor, not fuel cost. Now add autonomous flying to the mix and you solve that as well.