They find that when you perform an action, there is a EEG spike [2] in the motor cortex well before you actually consciously decide to perform the action. The experiment is conducted with a dot running around a circle and the subject has to tell when (as per where the dot was) he decided to act. The EEG potential is seen prior to that decision moment.
This is related to free-will as it is as if the decision of acting is not coming from your conscious self but from a deeper layer.
[1] Libet experiment: https://www.youtube.com/watch?v=OjCt-L0Ph5o
[2] Bereitschaftspotential: https://en.wikipedia.org/wiki/Bereitschaftspotential