Its a good thought, but you're excluding ~15% of all web users[0] from using your product.
* You are hosting an internal enterprise application and you are forcing all of your employee desktops to use Chrome any case.
* You are not serving a web site, but a business web app, which only works on a modern browser - because it is a business oriented app people are willing to switch the browser to use it. E.g. 3d modeler.