That's a version of the "negative income tax", like the current EITC, but not the one that Friedman proposed. His version refunds a proportion of unused deductions, and bottoms out at a guaranteed minimum income equal to the standard deduction times the refund rate.
In his version, there's an allowance calculated by family size, dependents, etc., and a "subsidy rate", which is the proportion of any excess allowance that's refundable. He proposed a 50% subsidy rate. If the allowance for a given taxpayer is $20,000, and the taxpayer earns $15,000, that leaves $5,000 in unused allowance, of which 50% is refunded, so the taxpayer gets a $2,500 transfer payment. If the taxpayer earns no income at all, the entire $20,000 is unused, of which 50% is refunded, so the taxpayer gets a $10,000 transfer payment.
So, if A is allowance, S is subsidy rate, and W is wages, the taxpayer earns W if W >= A, or W + S * (A-W) otherwise. The guaranteed minimum income is when W=0, and equal to S * A ($10,000 in the above example).
For Hayek, here's one of several places he discusses his rationale: http://books.google.com/books?id=nclLLOfnGqAC&pg=PA55. One reason is that, unlike many libertarians, he's strongly against private-sector safety nets through e.g. church charities, because he feels those inhibit human freedom by making people scared to leave their ethnic/religious/racial/social group for fear of losing its safety net, which he views as a variety of collectivism. So he sees a guaranteed minimum income as a way of promoting individual freedom and undermining the power of tribalist collectives.