No no, you also need to put the OPs guys who never programmed java or are even remotely interested into the dev team. Bonus points for devs who never did ops and don't care about it.
Also don't give both teams training and don't plan for increased development time by additional ops tasks!
Just call it "we put an ops guy in your team, you're devops now!". (coming from a devops guy, who loves to do both things)