Having a working intuition for relational databases is valuable on a deep level. I mean having a sense of how to organize the tables, what sizes are large and small, when to add what kind of index and what the size and speed limits are likely to be for a given data structure. That's extremely valuable.
BTW, we're preparing to move a postgres database that's a few TB from Heroku to AWS RDS. The catch is that we can't afford more than a few minutes of downtime. If this is in your wheelhouse, reach out! We'd like to talk.