The carbon reaction goes like this: Carbon + Oxygen = CO2 + energy.
You can reverse it, like you can with any chemical reaction, like this: CO2 + energy = Carbon + Oxygen
This is all high school chemistry stuff. But the long and short is: To sequester carbon from the atmosphere requires at least as much energy as you got by burning the carbon in the first place.
That's why no scheme to unburn the carbon can ever work.