If you give in to them too many times and end up with buggy code where trivial changes take a month, but has all the features that are needed where do you think the blame will fall? I can guarantee you it isn't going to be the business side.
The goal shouldn't be for the CTO to be the business side's technical henchman. It should be to look after the technical side of things. If a rewrite is the best decision technically (without considering the business), then that's what the CTO should advocate, but they need to be willing to work with the business side to find a solution that works for both sides.