- What version of the languages and frameworks are they using? If they're not current versions, why not and when do they plan to update?
- If they do automated testing find out if it's the whole code base or just on an isolated part.
- If they have QA, are they writing automated tests or just performing manual QA?
- How long does it take to get code deployed?
- What do they think their biggest technical issue is and how do they plan to address it? In your experience, do those things line up?
- Are you personally impressed by the knowledge level of the engineers interviewing you? That's not one you can ask directly, but you can get an idea by seeing how they answer.
Understanding what their processes look like in practice and in detail, as well as why and how they make decisions, can tell you an enormous amount about the effectiveness of the organization.