I switched because Firefox has Multi-Account Containers, which was extremely compelling.
This wasn't meant to be a plug, just a happenstance of "if you like 'x', have you seen 'y' based on it?". =]
[0] - https://addons.mozilla.org/en-US/firefox/addon/temporary-con...
Sadly, Mozilla also seem to promote containers as an alternative to user profiles, while they're nowhere near as full-featured - sharing saved logins and bookmarks between my "personal" and "work" containers is almost never desireable. Managing and switching profiles, on the other hand, is virtually unchanged since the Netscape Communicator days.