Django / Python sounds like the obvious answer. Almost every comparison between Rails and Django I have read seems to rate them fairly evenly.
Many people have had the experience of choosing a lightweight framework (Sinatra, Flask, etc.) and gradually needing more and more features from a heavier framework. Eventually you find that you wrote a poorly documented, poorly implemented version of Django or Rails, and bringing new people onto your team is now far harder than just finding people who've used a specific framework.