xkcd comics are already licensed under a Creative Commons Attribution-Noncommercial 2.5 license. That's probably all you need for a math team t-shirt.
Even if the current size was large enough, he would probably appreciate knowing about his work being printed like that as most people do.
No idea why it was initially downvoted, it's good information to point out. So long as you don't make money off the shirts, it's ok to use xkcd comics.