Magdeburg Hemispheres
en.wikipedia.org
en.wikipedia.org
Also the German comedian Otto Waalkes (https://en.wikipedia.org/w/index.php?title=Otto_Waalkes&oldi...) and Otto von Bismarck (https://en.wikipedia.org/wiki/Otto_von_Bismarck) - even though in opposite to Otto I and Otto von Guericke these two are not from Magdeburg.
I'm no expert, but if it was able to evacuate all of the air from the inside sounds unlikely - impossible, even. What's the best we could do nowadays? How total are (practical) vacuums?
The best multistage pumps can reach ~0.0001 mbar.[0]
Generally, attainable vacuum by pumping depends on leakage rate vs pump speed, and also on the vapor pressures of components. Such as oil used for lubrication, grease for sealing, rubber or plastic hoses, etc.
So for a high vacuum system, you want just metal and glass, and you want them to be very clean. Fingerprints are a huge issue. Also, you typically put a cold trap between your pump and the working volume. Both to get lower pressure, and to avoid contamination. For low vacuum, dry ice in acetone is OK. Then liquid nitrogen, and finally liquid helium.
0) https://cds.cern.ch/record/1046850/files/p43.pdf
Edit: It's important to avoid contamination of the working volume (say, by pump oil) and of the pump (say, by water, or corrosive substances).
One cubic millimeter is 1mm³.
Of course real air isn't quite an ideal gas, but some reasonable approximations [1] come out to 2.53E25 molecules (N2 and O2) per cubic meter at 15 C and 1 atm.
[1] https://www.quora.com/How-many-air-molecules-are-present-in-...
You have ~1 molecule per cubic meter at ~1E-25 bar.