No you cannot, unless you're running a single threaded server process on a single machine. What you can do is _gamble_ that you probably won't have a collision, which is the same thing you could do with regular UUIDs and you'd be (nearly) guaranteed to never hit a conflict with UUID4 (or probably UUID1/2 if you trusted your mac address uniqueness).
You may find this gamble acceptable and many people do, but you should be aware that pre-generation of UUIDs on independent systems without coordination is not a solvable problem - all attempts to do so rely on the extreme unlikelihood of a collusion to feel good about it or use some coordinated information (like a guaranteed unique mac address).
(Again, if it's good enough for you, right on - but it isn't theoretically safe)