This feature has been available in the dev channel of Chrome for ages, and until now it's still unstable. PDF's tend big documents, and it's generally the case that Chrome locks up and ends up crashing when opening a PDF that's more than a few pages. This defeats the purpose in my opinion. The moment I notice I'm loading a PDF in Chrome I go ballistic trying to close the tab to avoid the crash.
I'd rather have developers improving the bookmark manager than trying to make a browser a PDF reader also. And a bad one at it. This makes me want to go back to the Chromium nightly builds. Those where awesome and bullshit free.