Let's say the market is so bimodal that a startup fails or becomes google. Then the expected return is:
p * G
where 'p' is the chance of becoming Google, 'G' is Google's value.
Basically investors' bid for valuation is their bid for what p is.
The story is only that if they say that the company's value is X while the startup says it is 2 * X that means that they say p = p1 while the startup thinks p = 2 * p1
Of course valuations matter. It matters linearly. In any market. Even in the most risky markets. I can decrease my risk by diversifying my investments into lots of different high risk assets and my expected return remain the same, but I can only increase my expected return by buying in at low valuation. This is exactly what YCombinator does. This is just very basic math.
TL;DR: The fact that investors care about valuations does not mean they don't recognize that the success distribution is bimodal.