Energy demand is highest in the Winter, when mean monthly sunshine hours are at the lowest.
Even in Nice (the very south of France) where I assume this difference would be smaller, there's still a big gap between 347.5 mean hours in July and 139.3 mean hours in December (https://en.wikipedia.org/wiki/Nice#Climate).
Surely we'd need to heavily invest in backup generation capacity that would be dormant for the vast majority of the summer then heavily in use over the winter?
Admittedly I have a very limited amount of knowledge in this area - but wouldn't wind or tidal power generation be a better bet here (well, Europe anyway)?