Stock certificates in private companies are not bearer-coupons (i.e., even if I get my hands on your certificate, that does not make me the owner of your shares).
Furthermore, in 42 states, the board of directors can issue equity shares with a simple amendment to the the company's Operating Agreement.
Finally, if the company was operating in one of the 8 states where that's not allowed, or decided to do certificates anyway, the recipients of that equity should not have had the certificates in their hands for long (i.e., they get issued, the recipient has to sign and return within a few days).
So the idea that the certs are floating around out there and must be returned immediately for an acquisition is suspicious.