Such a pipe would have to be placed with water inside, then pumped out once its installed. Why? Because it takes a lot of force to put an air-filled tube through water.
I see no way that such a pipe could be deployed. Even without buoyancy issues, there will be a lot of friction from the cave walls, and going around bends. The force can't come from simply pushing it it, as anything flexible enough to bend around curves will also crumble from the pushing force.
If I read it right, the pipe would need to be 6 meters deep in some points in the cave. As you might recall from Star Trek IV The Voyage Home, the transparent aluminum scene, the whale tank needed 6" of Plexiglass. If I use the "Aquarium Thickness Calculator (xls)" from http://www.sdplastics.com/aquaria1.html and plug in 200 inches (for about 6 meters), then it says it would need 16 inches of Plexiglass.
You might shave that down, with better materials that don't need to be clear, but, as The Guardian points out elsewhere, there isn't much room: "Parts of the cave system are reportedly so narrow that Thai Seal teams and the volunteer rescue divers had to remove their own breathing apparatus to get through"
Furthermore: "It’s about 11 hours – six on the way from the entrance to where the kids are and five on the way back"
Who will guide the pipe at it goes through the route? Once the pipe has gone through one of those constrictions, can anyone else get by? If the pipe blocks the route, then what?
And, how long would it take to lay such a pipe?