Normal houses aren't purely full of standard things. People have round chair-like things, oval bassinets, exercise equipment, oval dog beds, funny-shaped cat scratch posts, round potted plants, and so on. Put this stuff beside the curved walls.
Each room in a dome home will normally have at least 2 flat walls, frequently 3. That's enough for shoving things against walls, not that you should damage your paint that way.
Usually people use normal windows and doors. You can install them the ugly way or the pretty way, and oddly there are people who choose both. The ugly way has them on bulging protrusions. The pretty way has them recessed behind openings that are often rectangles or trapezoids with rounded corners, with the space between acting as a balcony or sheltered porch.
Here is a pretty one on sale now, having gone up in value by more than a factor of 8:
https://www.islandpacket.com/news/business/real-estate-news/...
http://www.monolithic.org/homes/featured-homes/the-eye-of-th...