In "The Promise of Sleep", the author talks about naps and getting tired in the afternoon, and his conclusion is that the only reason people get tired in the afternoon (which is when your clock-dependent alerting is at its lowest) is because they are sleep deprived. If you are well rested and don't have sleep debt, you should not get tired at that time.
Having consciously tried to get enough sleep over the past 2 years or so, I believe he's right. These days, I barely notice any afternoon dip and when I do, it's when my sleep has been disturbed for some reason.