It would be interesting to chat with the people responsible for those pieces to get a sense of what they knew about Kahlo and what attributes about her they find interesting. I have a similar hunch that many of the people plastering her face around the city probably actually know fairly little about her.
I think that's okay.
That meaning you're touching on by asking, which is what commerce means in relationship with the arts, is graduate-level theory that you could doctorate in, and remains one of the most debated topics in modern times with the unique twist of cultural leaders outside academia usually being the voices that teach us well. Try concretely defining cultural exploitation, for example, in a way that sets aside personal perspective on the concept. I'd contend it's insoluble.