I think that’s good as a rule, but I’m not sure it holds for cases like Joyce. If you want to write a book that has to do with how experience is translated into language and vice-versa, transparent language might not be best. Sometimes confusion can be a very deliberate and controlled effect, like in David Foster Wallace (who’s also on the front page today).
Just like Picasso could draw a realistic portrait when he wanted, Joyce sometimes used very simple and conservative prose. But I would agree that most people who use long words (like most people who use more than one perspective per painting) shouldn’t.