This is what would be scaring me more than any of the debts. Almost no bank will open a new merchant account for him if he's on TMF/MATCH, and that includes if he's just one of several owners of a future company -- merchant account applications ask for a list of all principals for just this reason. He'll find his way out of the debt problem, whether it's through bankruptcy or repayment, but being listed on TMF/MATCH can prevent him from starting a new business that accepts credit cards for the rest of his life.
but he's not a company. and if he starts another one he can list somebody (or pretty much anybody) else as principal if I understand correctly:
http://answers.yahoo.com/question/index?qid=20070909074529AA...