A Gentle Introduction to CouchDB for Relational Practitioners
blog.couchone.com
blog.couchone.com
Side comment: learning to write map reduce algos instead of just querying was kind of difficult at first (for document databases in general). The article seems to have neglected to mention it -- it had the steepest learning curve in the overall couch-learning process for me.
haven't used this but i saw this on SO the other day ... I just started looking at the whole NoSQL paradigm to experiment in the near future and i felt it was helpful to track some tags on StackOverflow to learn about issues people face...
Oh yeah, and Futon is an awesome tool. On some of the sites where I've been too lazy to build CMS tools, I'm just using it to update the site, and it works quite well for that. It also makes it easy to just jump in and fix something up whenever you need to.